Visible-Light Photocatalysis Promoted by Solid-and Liquid-Phase Immobilized Transition Metal Complexes in Organic Synthesis

Alexei Yakushev (1) , Anton S. Abel (1) , Alexei D. Averin (1) , Irina P. Beletskaya (1, 2) , Andrey V. Cheprakov (1) , Ilia S. Ziankou (1) , Laurent Bonneviot (3) , Alla G. Bessmertnykh-Lemeune (4)

1 Department of Chemistry, Lomonosov Moscow State University
2 A.N. Frumkin Institute of Physical Chemistry and Electrochemistry
3 LC - Laboratoire de Chimie - UMR5182
4 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

This review summarizes synthetic approaches to reusable photocatalytic systems based on visible light-active transition metal complexes with chelating ligands containing pyridyl residues such as 2,2′-bipyridines, 1,10-phenanthrolines, 2,2′:6′,2′′-terpyridines and related ligands. The use of these materials in organic synthesis is then discussed focusing on 1) most active systems exhibiting a synergy effect between photophysical properties of immobilized complexes and photoactive solid supports and 2) the possibility of repeated uses of the developed catalytic system.

Mots clés: photoactive metal complex; reusable catalyst; visible light-driven catalysis; functional material; photoredox catalyst; sustainable organic reaction

Domaines: Chimie de coordination; Catalyse

Alexei Yakushev, Anton S. Abel, Alexei D. Averin, Irina P. Beletskaya, Andrey V. Cheprakov, et al.. Visible-Light Photocatalysis Promoted by Solid-and Liquid-Phase Immobilized Transition Metal Complexes in Organic Synthesis. Coordination Chemistry Reviews, 2022, 458, pp.214331. ⟨10.1016/j.ccr.2021.214331⟩. ⟨hal-03759523⟩