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Journal articles
Synthesis and Properties of Higher Nuclearity Polyazanes
Abstract : Polyazanes (that is, higher nuclearity homologues of hydrazines) with increasing numbers of bound nitrogen atoms (from 3 to 5) were prepared via additions of lower order polyazanes to diazo reagents, including the first pentazane ever described. A structure was obtained. It was shown that the polynitrogen chains adopt a helical conformation. DFT modeling shows that the arrangement subsists in solution. While the polyazanes are all reducing agents, they become less so with the increasing number of nitrogens.
https://hal-univ-lyon1.archives-ouvertes.fr/hal-03089670
Contributor : Emmanuel Lacôte <>
Submitted on : Monday, December 28, 2020 - 5:24:38 PM
Last modification on : Friday, June 25, 2021 - 7:38:02 PM
Long-term archiving on: : Monday, March 29, 2021 - 6:47:52 PM
Contributor : Emmanuel Lacôte <>
Submitted on : Monday, December 28, 2020 - 5:24:38 PM
Last modification on : Friday, June 25, 2021 - 7:38:02 PM
Long-term archiving on: : Monday, March 29, 2021 - 6:47:52 PM
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Angew-Thomas-2019-DEF.pdf
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