Skip to Main content Skip to Navigation
New interface
Journal articles

Synthesis and Properties of Higher Nuclearity Polyazanes

Abstract : Polyazanes (that is, higher nuclearity homologues of hydrazines) with increasing numbers of bound nitrogen atoms (from 3 to 5) were prepared via additions of lower order polyazanes to diazo reagents, including the first pentazane ever described. A structure was obtained. It was shown that the polynitrogen chains adopt a helical conformation. DFT modeling shows that the arrangement subsists in solution. While the polyazanes are all reducing agents, they become less so with the increasing number of nitrogens.
Document type :
Journal articles
Complete list of metadata
Contributor : Emmanuel Lacôte Connect in order to contact the contributor
Submitted on : Monday, December 28, 2020 - 5:24:38 PM
Last modification on : Tuesday, September 27, 2022 - 4:29:30 AM
Long-term archiving on: : Monday, March 29, 2021 - 6:47:52 PM


Files produced by the author(s)


  • HAL Id : hal-03089670, version 1


Thomas Criton, Debora Vilona, Guy Jacob, Maurice Médebielle, Elise Dumont, et al.. Synthesis and Properties of Higher Nuclearity Polyazanes. Chemistry - A European Journal, 2020. ⟨hal-03089670⟩



Record views


Files downloads