Thermal and Optical Characterization of Undoped and Neodymium-Doped Y3ScAl4O12 Ceramics - Université Claude Bernard Lyon 1 Accéder directement au contenu
Article Dans Une Revue Journal of Physical Chemistry C Année : 2014

Thermal and Optical Characterization of Undoped and Neodymium-Doped Y3ScAl4O12 Ceramics

Résumé

Y3–3xNd3xSc1Al4O12 (x = 0, 0.01, and 0.02) ceramics were fabricated by sintering at high temperature under vacuum. Unit cell parameter refinement and chemical analysis have been performed. The morphological characterization shows micrograins with no visible defects. The thermal analysis of these ceramics is presented, by measuring the specific heat in the temperature range from 300 to 500 K. Their values at room temperature are in the range 0.81–0.90 J g1–K–1. The thermal conductivity has been determined by two methods: by the experimental measurement of the thermal diffusivity by the photopyroelectric method, and by spectroscopy, evaluating the thermal load. The thermal conductivities are in the range 9.7–6.5 W K–1 m–1 in the temperature interval from 300 to 500 K. The thermooptic coefficients were measured at 632 nm by the dark mode method using a prism coupler, and the obtained values are in the range 12.8–13.3 × 10–6 K–1. The nonlinear refractive index values at 795 nm have been evaluated to calibrate the nonlinear optical response of these materials.

Dates et versions

hal-02309843 , version 1 (09-10-2019)

Identifiants

Citer

M. C. Pujol, Alexandre Maître, Julie Carreaud, Rémy Boulesteix, Alain Brenier, et al.. Thermal and Optical Characterization of Undoped and Neodymium-Doped Y3ScAl4O12 Ceramics. Journal of Physical Chemistry C, 2014, 118 (25), pp.13781-13789. ⟨10.1021/jp5027493⟩. ⟨hal-02309843⟩
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