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Copper complexes bearing an NHC-calixarene unit: synthesis and application in click chemistry

Abstract : The synthesis of N-heterocyclic carbene (NHC) copper complexes supported by calix[4]arene is reported. Mono-substituted calix[4]arene was prepared through conventional procedures, followed by the attachment of an imidazolyl group to create the precursor of NHC ligands. Alkylation with two alkyl bromides followed by metalation resulted in fully characterized original complexes. The X-ray structure showed an “out” conformation for copper. The catalytic activity of the complexes was studied in click chemistry, and revealed good performances. In particular, three new triazoles were synthesized in high yields, under solvent-free conditions and a fast reaction time. The newly synthesized chiral complex was tested in the kinetic resolution of racemic azide.
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https://hal-univ-lyon1.archives-ouvertes.fr/hal-02290207
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Submitted on : Tuesday, September 17, 2019 - 2:48:44 PM
Last modification on : Thursday, April 2, 2020 - 10:48:06 AM

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Benjamin Ourri, Olivier Tillement, Tao Tu, Erwann Jeanneau, Ulrich Darbost, et al.. Copper complexes bearing an NHC-calixarene unit: synthesis and application in click chemistry. New Journal of Chemistry, Royal Society of Chemistry, 2016, 40, pp.9477-9485. ⟨10.1039/c6nj02089e⟩. ⟨hal-02290207⟩

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