Anisotropy evolution of nanoparticles under annealing: Benefits of isothermal remanent magnetization simulation

Florent Tournus (1) , Alexandre Tamion (1) , Arnaud Hillion (1) , Veronique Dupuis (1)

1 ILM - Institut Lumière Matière [Villeurbanne]

Isothermal remanent magnetization (IRM) combined with Direct current demagnetization (DcD) are powerful tools to qualitatively study the interactions (through the Δm parameter) between magnetic particles in a granular media. For magnetic nanoparticles diluted in a matrix, it is possible to reach a regime where Δm is equal to zero, i.e. where interparticle interactions are negligible: one can then infer the intrinsic properties of nanoparticles through measurements on an assembly, which are analyzed by a combined fit procedure (based on the Stoner–Wohlfarth and Néel models). Here we illustrate the benefits of a quantitative analysis of IRM curves, for Co nanoparticles embedded in amorphous carbon (before and after annealing): while a large anisotropy increase may have been deduced from the other measurements, IRM curves provide an improved characterization of the nanomagnets intrinsic properties, revealing that it is in fact not the case. This shows that IRM curves, which only probe the irreversible switching of nanomagnets, are complementary to widely used low field susceptibility curves.

Domaines: Chimie; Physique [physics]; Sciences de l'ingénieur [physics]

Florent Tournus, Alexandre Tamion, Arnaud Hillion, Veronique Dupuis. Anisotropy evolution of nanoparticles under annealing: Benefits of isothermal remanent magnetization simulation. Journal of Magnetism and Magnetic Materials, 2016, 419, pp.1-4. ⟨10.1016/j.jmmm.2016.06.005⟩. ⟨hal-02289465⟩