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Journal articles
Thiolation of NHC-boranes: influence of the substitution at boron
Abstract : Several N-Heterocyclic Carbene (NHC)-boryl sulfides with B-substituents were prepared. The added steric hindrance leads to much improved selectivities as only the NHC-boryl mono-sulfides were obtained. The B-substituted NHC-boranes are also conducive to more selective S to N NHC-boryl shift, provided that the NHC used is not too sterically demanding.
Cited literature [22 references]
https://hal-univ-lyon1.archives-ouvertes.fr/hal-02104323
Contributor : Emmanuel Lacôte Connect in order to contact the contributor
Submitted on : Friday, April 19, 2019 - 2:31:59 PM
Last modification on : Tuesday, January 4, 2022 - 6:29:19 AM
Contributor : Emmanuel Lacôte Connect in order to contact the contributor
Submitted on : Friday, April 19, 2019 - 2:31:59 PM
Last modification on : Tuesday, January 4, 2022 - 6:29:19 AM
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