Thiolation of NHC-boranes: influence of the substitution at boron

Anne-Laure Vallet; Emmanuel Lacote

Thiolation of NHC-boranes: influence of the substitution at boron

Anne-Laure Vallet Emmanuel Lacote ^{1, *}

* Corresponding author

1 C2P2 - Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265

Abstract : Several N-Heterocyclic Carbene (NHC)-boryl sulfides with B-substituents were prepared. The added steric hindrance leads to much improved selectivities as only the NHC-boryl mono-sulfides were obtained. The B-substituted NHC-boranes are also conducive to more selective S to N NHC-boryl shift, provided that the NHC used is not too sterically demanding.

Document type :

Journal articles

Domain :

Chemical Sciences / Organic chemistry

Complete list of metadatas

Cited literature [22 references] Display Hide Download

https://hal-univ-lyon1.archives-ouvertes.fr/hal-02104323
Contributor : Emmanuel Lacôte <>
Submitted on : Friday, April 19, 2019 - 2:31:59 PM
Last modification on : Tuesday, August 6, 2019 - 7:19:20 PM

NHCB-SH-BSubst-TEXT (1).pdf

Files produced by the author(s)

Thiolation of NHC-boranes: influence of the substitution at boron

Files

Identifiers

Collections

Citation

Export

Metrics

25

40

Contact

Thiolation of NHC-boranes: influence of the substitution at boron

Files

Identifiers

Collections

Citation

Export

Share

Metrics

25

40

Contact