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Journal articles
Further insight in the minor/major concept using hydrogen pressure effect in asymmetric hydrogenation
Abstract : The catalytic system prepared from [Rh(COD)(2)]BF4 and (R,R)-Me-BPE provides a spectacular detrimental hydrogen pressure effect on ee from 94% down to 56% in the hydrogenation of methylacrylate, whereas it has a strong beneficial effect on the hydrogenation of E-emap (from 42% up to 72%). The kinetic parameters have been determined for both systems and have helped to identify the most enantioselective controlling steps (MECS). Accordingly, further explanations for the structure-ee and hydrogen pressure relationship are proposed. (c) 2012 Elsevier B.V. All rights reserved.
https://hal-univ-lyon1.archives-ouvertes.fr/hal-01923743
Contributor : Lauriane Pillet Connect in order to contact the contributor
Submitted on : Thursday, November 15, 2018 - 2:02:28 PM
Last modification on : Tuesday, December 7, 2021 - 12:22:03 PM
Contributor : Lauriane Pillet Connect in order to contact the contributor
Submitted on : Thursday, November 15, 2018 - 2:02:28 PM
Last modification on : Tuesday, December 7, 2021 - 12:22:03 PM